This may be a result of the lamp operating at a higher temperature than designed for: In that case the higher pressure makes the bluish-green from the discharge relatively stronger to the part generated from the UV. Second effect related to the temperature is the shift of the phosphor radiation towards the shorter wavelengths. The higher temperature could be either inadequate ventilation in the fixture (the fixture thermal design may count on the majority of the heat from the incandescents coming as an IR radiation and just let this pass out, while majority of heat from the fluorescents is convection and that lead to excessive heat accumulation within the fixture; and the incandescents have generally less problems with high temperature, so the fixture may be just designed to operate that hotter, but the fluorescents already degrade their performance).
Or it could be just the fact the design count on the mercury to migrate to the lowest (so usually coldest) spot in the tube, until then the pressure could be higher than designed. If this is the case, it will require some time to settle, to adopt the exact burning position of the lamp.
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