As both ends blackened and the lamp working with cold cathodes, these areas overheats, and tiny cracks forms. This can cause impurities to get into the tube.
Freezing the lamp and than operate it, can results in similar cracks. This was happened once to me with one of my Osram HWL 160W after freezing it:
https://www.lighting-gallery.net/gallery/displayimage.php?pos=-75963